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Ruminants produced a huge variety of C10-C18 acids with one to four neutral lipids branched methyl groups, they were detected in lamb adipose tissue. Multimethyl branched acids are also dominant in the uropygial waxes of the birds preen gland. Curiously, they were also identified in the lipid depot in the neutral lipids head of marine animals, location involved in their echo-locating abilities. Unusual branched fatty acids have been isolated as minor components from the glycolipids (GL) fraction of freshwater sponges (Dembitsky VM et al., Chem Phys Lipids 2003, 123, 117).It is possible that these neo acids could be of cyanobacterial origin. An neutral lipids example of one of them with the longest carbon chain is shown below. Others have isoprenoid structures, thus coming from the diterpene phytol derived from chlorophyll and not by the de novo pathway.
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